The trans-dioxo ruthenium (VI) complex, [P(C6H5)3C6H5CH 2]+[Ru(O)2OAcCl2]- or tetrapropylammonium perruthenate catalyzes the oxidation of secondary alcohols to ketones by N-methylmorpholine-N-oxide (NMO). Kinetic studies showed the formation of a complex between catalyst and substrate (alcohol) as the first step in the mechanism. © Akadémiai Kiadó,All rights reserved.

Venkatanarayana Mahadevan

Jayaraman Rajaram

C. S. Swamy

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

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Journal	Data powered by TypesetReaction Kinetics and Catalysis Letters
Publisher	Data powered by TypesetSpringer Netherlands
ISSN	01331736
Open Access	No