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Nano-scale Si segregation and precipitation in Cr 2 Al(Si)C MAX phase coatings impeding grain growth during oxidation
, Chang K., Kovács A., S Sen, Marshal A., de Kloe R., Dunin-Borkowski R.E., Schneider J.M.
Published in Taylor & Francis
2019
Volume: 7
   
Issue: 5
Pages: 180 - 187
Abstract
We recently reported that the columnar grain width of Cr 2 AlC MAX phase coatings increases during oxidation (4 h at 1120°C) by 80%, while for 0.7 at.% Si additions to Cr 2 AlC, coarsening of only 12% was observed. Here, we use nm scale compositional and microstructural investigations to identify significant differences between Cr 2 AlC and Cr 2 Al(Si)C. In particular, needle-shaped precipitates coarsen into globular Cr 3 Si precipitates upon oxidation in the Si-containing MAX phase. We infer that the presence of these precipitates, which are located predominantly along grain boundaries in the MAX phase, retards coarsening during oxidation by Zener pinning. © 2019, © 2019 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.
About the journal
JournalMaterials Research Letters
PublisherTaylor & Francis
Open AccessNo