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Magnetocaloric properties and critical exponents in anti-PbFCl type ZnMnSb room temperature ferromagnet prepared via different routes
Deepak Kumar Dinkar, Raghavan Gopalan, B. Das
Published in Elsevier B.V.
2019
Volume: 489
   
Abstract
We report the synthesis and magnetocaloric properties of ternary intermetallic compound ZnMnSb, which crystallizes in tetragonal crystal structure with the space group of P4/nmm. It undergoes a second order phase transition from ferromagnetic to paramagnetic at Curie temperature (Tc) of 302 and 293 K for arc melted and rapid thermal quenched ZnMnSb samples respectively under an applied field of 500 Oe. The maximum change in isothermal magnetic entropy (−ΔSM) with typical values of 1.3 and 0.8 J/kg K are found at Tc for arc melted and rapid thermal quenched samples respectively under an applied field of 20 kOe. The relative cooling power (RCP) calculated from the (−ΔSM) vs. T distribution plots are in the range of 43–48 J/kg. The critical behavior of ZnMnSb has been explained using the Arrott plots, field dependence of magnetization at Tc and temperature dependence of magnetization. The obtained values of the critical exponents δ and β are 3.385 and 0.154 for arc melted; and 2.850 and 0.102 for rapid thermal quenched samples respectively indicating that there exists a long range magnetic interaction below Tc. The moderate −ΔSM at low applied field along with broad operating temperature range, the Tc close to room temperature and the low cost of ZnMnSb make it a promising candidate for room temperature magnetic cooling applications. © 2019 Elsevier B.V.
About the journal
JournalData powered by TypesetJournal of Magnetism and Magnetic Materials
PublisherData powered by TypesetElsevier B.V.
ISSN03048853
Open AccessNo
Concepts (22)
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    Crystal structure
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    Ferromagnetic materials
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    Ferromagnetism
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    Lead compounds
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    Magnetic materials
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    Magnetization
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    Magnetocaloric effects
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    Manganese compounds
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    Technetium
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    Temperature distribution
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    Zinc compounds
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    Critical exponent
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    OPERATING TEMPERATURE RANGES
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    Second orders
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    SECOND-ORDER PHASE TRANSITION
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    TERNARY INTERMETALLIC COMPOUND
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    Tetragonal crystal structure
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    ZNMNSB
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    Fluorine compounds