The kinetics of oxidation of vanadium(III) by hydroxylamine have been investigated at high acidities in the temperature range 25-30 °C. Rates decreased with increasing acidity of the medium. Both NH2OH and NH3OH+ are capable of oxidizing V(III) in parallel reactions, the order being unity each in oxidant and reductant. © 1982 Akadémiai Kiadó.

Venkatanarayana Mahadevan

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Kinetics of oxidation of vanadium(III) by hydroxylamine in acid medium

Reaction Kinetics and Catalysis Letters

Kinetics of oxidation of Tris-acetylacetonato V(III) by hydroxylamine in DMF and the polymerization of acrylamide have been investigated in the temperature range 20-30°C. The oxidation is a second order process with polymerization being initiated and terminated by the amino radicals. Rate and thermodynamic data have been evaluated and their significance discussed. © 1981.

European Polymer Journal

Redox polymerization of acrylamide initiated by the system V(III)(acac)3 hydroxylamine in dimethyl formamide

Journal of Inorganic and Nuclear Chemistry

Kinetic study on the reduction of hydroxylamine by V(III)

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry

Effect of pH on the kinetics of the reduction of hydroxylamine by Ti(III)

Inorganic Chemistry

Oxidations of aqueous chromium(II). I. Hydroxylamine and some amine oxides

Journal of the Chemical Society A: Inorganic, Physical, Theoretical

The kinetics of the reaction of chromium(II) with hydrazine, hydroxylamine and hydrazoic acid in perchlorate media: the formation of halogeno- and sulphato-complexes of chromium(II)

Journal	Reaction Kinetics and Catalysis Letters
Publisher	Kluwer Academic Publishers
ISSN	01331736
Open Access	No