An optical method using the Kerr effect is reported for the measurement of high voltage transient pulses with benzonitrile, acrylonitrile, propionitrile, butyronitrile and m-nitrotoluene for the first time along with nitrobenzene and acetone that are well known. These investigations have been performed using high voltage pulse fields ranging from 5 x 105 vm"1 to 107 vm-1. The experimentally measured values of the electric field from the Kerr signals are found to be in excellent agreement with applied field. © 1995 The Japan Society of Applied Physics.