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Hydroprocessing of sunflower oil-gas oil blends over sulfided Ni-Mo-Al-zeolite beta composites
Marimuthu Banu, Subramanian Sivasanker
Published in
2011
PMID: 21945166
Volume: 102
   
Issue: 22
Pages: 10717 - 10723
Abstract
Mixtures of sunflower oil and a straight run gas oil in the diesel fuel range were hydroprocessed over sulfided NiO(3%)-MoO 3(12%)-γ-Al 2O 3 incorporating 0, 15 or 30wt.% zeolite beta (BEA). The studies were carried out at 320-350°C; 30-60bars, and weight hourly space velocities (WHSV), 1-4h -1. Catalyst containing 30% BEA achieved nearly 100 % conversion of the vegetable oil into hydrocarbons at 330°C, 60 bars and a WHSV of 2h -1 compared to 95.5% by the Ni-Mo-γ-alumina catalyst without BEA. Hydroprocessing with blends containing oleic acid revealed that the catalysts were able to transform the acid into hydrocarbons. An analysis of the ratios of the n-C 18 and n-C 17 paraffins formed from the vegetable oil at different process conditions revealed that the catalyst containing 15% BEA was most active for hydrodeoxygenation. The gas oil-hydrodesulfurization activity of the Ni-Mo-Al 2O 3 was enhanced by the addition of BEA by more than 10%. © 2011 Elsevier Ltd.
About the journal
JournalBioresource Technology
ISSN09608524
Open AccessNo
Concepts (65)
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    ALUMINA CATALYSTS
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    BETA ZEOLITE
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    DIFFERENT PROCESS
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    HYDRODEOXYGENATION
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    HYDROPROCESSING
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    NI-MO-ALUMINA
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    STRAIGHT RUN GAS OIL
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    Sunflower oil
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    WEIGHT HOURLY SPACE VELOCITY
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    ZEOLITE BETA
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    Aluminum
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    CATALYSTS
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    Diesel fuels
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    Gas oils
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    HYDRODESULFURIZATION
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    LUBRICATING OILS
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    Molybdenum oxide
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    Oleic acid
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    Organic compounds
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    Paraffins
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    Vegetable oils
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    HYDROCRACKING
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    Aniline
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    Biodiesel
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    Hydrocarbon
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    Molybdenum
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    Nanocomposite
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    Nickel
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    PARAFFIN
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    Sulfide
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    Zeolite
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    Alkane
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    Aluminum oxide
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    Catalyst
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    Composite
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    Diesel
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    Fatty acid
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    Natural gas
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    Petroleum
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    Pressure gradient
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    Reaction kinetics
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    Sulfur
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    Transformation
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    Vegetable oil
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    Article
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    Chemical composition
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    Density
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    Desulfurization
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    Distillation
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    Oxygenation
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    Priority journal
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    Velocity
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    Viscosity
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    Biotechnology
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    Catalysis
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    Fatty acids
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    Gases
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    Gasoline
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    Hydrogenation
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    Oxides
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    PLANT OILS
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    Sulfides
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    X-ray diffraction
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    Zeolites
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    HELIANTHUS