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High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle
Published in
2011
Volume: 17
   
Issue: 15
Pages: 4081 - 4084
Abstract
Coupled cluster: An unprecedented 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster is accessible from a borole precursor in two steps involving a mild reduction process. The title compound consists of a perphenylated cluster framework, which is linked to an exo-polyhedral boracycle. This was confirmed by NMR spectroscopy and X-ray crystallography. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
About the journal
JournalChemistry - A European Journal
ISSN09476539
Open AccessNo
Concepts (13)
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    BOROLE
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    CARBORANES
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    CLUSTER FRAMEWORK
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    Coupled clusters
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    HIGH YIELD SYNTHESIS
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    Nmr spectroscopy
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    ORGANOBORANE
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    Reduction process
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    Title compounds
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    Boron
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    Boron compounds
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    Nuclear magnetic resonance spectroscopy
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    X ray crystallography