The borate radical is produced by the flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8. The absorption spectrum of the transient borate radical shows two maxima. The self decay of this radical is second order. Rate constants for the reactions of this radical with some organic substrates have been determined. © 1988 Indian Academy of Sciences.

Jayaraman Rajaram

Joseph C. Kuriacose

IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

IIT Madras

Generation and reactions of the borate radical — A flash photolysis study

Proceedings of the Indian Academy of Sciences - Chemical Sciences

Carbonate radicals react with aliphatic amines by a dual mechanism, viz. (i) hydrogen abstraction and (ii) electron transfer. The former is more probable with primary amines. Tertiary amines react via electron transfer. Both mechanisms may operate in secondary amines. Cyclic tertiary amines react with different rates and their relative reactivities are explained on the basis of the concept of Hoffmann's 'through bond' interaction. © 1985.

Tetrahedron

Reactions of the carbonate radical with aliphatic amines

Inorganic Chemistry

High-field boron-11 NMR of alkali borates. Aqueous polyborate equilibria

Russian Chemical Reviews

Inorganic Radical-ions and Their Organic Reactions

Identification of polyborate and fluoropolyborate ions in solution by Raman spectroscopy

The Journal of Physical Chemistry

Carbonate radical in flash photolysis and pulse radiolysis of aqueous carbonate solutions

Generation and reactions of the borate radical - A flash photolysis study

Journal	Data powered by TypesetProceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher	Data powered by TypesetSpringer India
ISSN	03700089
Open Access	No