Novel foam composites comprising functionalized graphene (f-G) and polyvinylidene fluoride (PVDF) were prepared and electrical conductivity and electromagnetic interference (EMI) shielding efficiency of the composites with different mass fractions of f-G have been investigated. The electrical conductivity increases with the increase in concentration of f-G in insulating PVDF matrix. A dramatic change in the conductivity is observed from 10 -16 S · m-1 for insulating PVDF to 10-4 S · m-1 for 0.5 wt.% f-G reinforced PVDF composite, which can be attributed to high-aspect-ratio and highly conducting nature of f-G nanofiller, which forms a conductive network in the polymer. An EMI shielding effectiveness of ≈20 dB is obtained in X-band (8-12 GHz) region and 18 dB in broadband (1-8 GHz) region for 5 wt.% of f-G in foam composite. The application of conductive graphene foam composites as lightweight EMI shielding materials for X-band and broadband shielding has been demonstrated and the mechanism of EMI shielding in f-G/PVDF foam composites has been discussed. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.