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Fine Copper Nanoparticles on Amine Functionalized SBA-15 as an Effective Catalyst for Mannich Reaction and Dye Reduction
Balasubramanian Viswanathan
Published in Springer New York LLC
2019
Abstract
Abstract: Copper nanoparticles dispersed on amine functionalised mesoporous silica SBA-15 (Cu/NH2-SBA-15) were synthesised by a simple sol–gel and impregnation method using sodium borohydride (NaBH4) as a reducing agent. The morphology, mesostructure and functionality of the ordered mesoporous Cu/NH2-SBA-15 were evaluated by powder X-ray diffraction (PXRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Nitrogen adsorption–desorption isotherms (BET) and Fourier transform infrared spectroscopy (FTIR). The results obtained revealed, that the amine functionalised SBA-15 holds hexagonal lamelliform with surface area and pore size of 250 m2/g, 2.2 nm respectively. Moreover, these short vertical channels have a substantial role in the uniform dispersion of copper nanoparticles within the meso-channels of amine functionalised SBA-15. Cu nanoparticles in the size range of 4–7 nm were dispersed on the NH2-SBA-15 support. To confirm the potential catalytic activity, Cu/NH2-SBA-15 was tested in Mannich reaction. The catalyst showed an excellent catalytic activity for the yield (90%) of β-amino carbonyl compounds that serve as a building block for the synthesis of lactams, peptides, amino alcohols and precursor for various amino acids. Further, the activity of the catalyst was also tested for the reduction of dyes. The structural influence over the reduction pathways was studied on triphenyl methane dyes. Graphical Abstract: [Figure not available: see fulltext.]. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.
About the journal
JournalData powered by TypesetJournal of Inorganic and Organometallic Polymers and Materials
PublisherData powered by TypesetSpringer New York LLC
ISSN15741443
Open AccessNo
Concepts (23)
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    Amides
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    Carbonyl compounds
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    Chemical reactions
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    Copper
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    Fourier transform infrared spectroscopy
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    Gas adsorption
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    High resolution transmission electron microscopy
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    Metal nanoparticles
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    Morphology
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    Pore size
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    Scanning electron microscopy
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    Silica
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    Sodium borohydride
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    Sols
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    AMINE FUNCTIONALIZATION
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    AMINE-FUNCTIONALIZED SBA-15
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    Copper nanoparticles
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    DESORPTION ISOTHERMS
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    MANNICH REACTIONS
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    POWDER X-RAY DIFFRACTION (PXRD)
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    SBA-15
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    STRUCTURAL INFLUENCES
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    Catalyst activity