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The two-coordinate germanium cation [(IDipp){(Me3Si)2CH}Ge:]+ has been synthesized, which lacks π-donor stabilization of the metal center and consequently has a very small HOMO–LUMO gap (187 kJ mol−1). It undergoes a variety of facile oxidative bond-forming reactions, most notably allowing access to the first examples of Group 14 metal cations containing ME multiple bonds (E=C, N). The use of an electrostatic (rather than purely steric) strategy to discourage aggregation means that less bulky systems (for example, containing a primary alkylidene fragment, CHR) are accessible.
Journal | Data powered by TypesetGerman Chemical Society |
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Publisher | Data powered by TypesetWiley |
Open Access | No |