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Experimental analysis of spatio-temporal behavior of anodic dead-end mode operated polymer electrolyte fuel cell
Published in
2011
Volume: 196
   
Issue: 23
Pages: 9931 - 9938
Abstract
During the anodic dead-end mode operation of fuel cells, the inert gases (nitrogen and water) present in the cathode side gas channel permeate to the anode side and accumulate in the anode gas channel. The inert gas accumulation in the anode decreases the fuel cell performance by impeding the access of hydrogen to the catalyst. The performance of fuel cell under potentiostatic dead-end mode operation is shown to have three distinct regions viz. time lag region, transient current region and a steady state current region. A current distribution measurement setup is used to capture the evolution of the current distribution as a function of time and space. Co- and counter-flow operations of dead-end mode confirm the propagation of inert gas from the dead-end of anode channel to the inlet of anode. Experiments with different oxidants, oxygen and air, under dead-end mode confirm that nitrogen which permeates from cathode to anode causes the performance drop of the fuel cell. For different starting current densities of 0.15 A cm-2, 0.3 A cm-2 and 0.6 A cm-2 the inert gas occupies 35%, 45% and 57%, respectively of anode channel volume at the end of 60 min of dead-end mode operation. © 2011 Elsevier B.V. All rights reserved.
About the journal
JournalJournal of Power Sources
ISSN03787753
Open AccessNo
Concepts (29)
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    ANODE CHANNELS
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    ANODE GAS
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    ANODE SIDE
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    ANODIC DEAD-END MODE
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    Current distribution
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    CURRENT DISTRIBUTION MEASUREMENT
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    Experimental analysis
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    FUEL CELL PERFORMANCE
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    Function of time
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    GAS ACCUMULATION
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    GAS CHANNELS
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    MODE OPERATION
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    NITROGEN ACCUMULATION
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    Polymer electrolyte fuel cells
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    Potentiostatics
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    Spatio-temporal
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    SPATIOTEMPORAL BEHAVIORS
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    STEADY-STATE CURRENTS
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    TIME LAG
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    Transient current
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    Cathodes
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    ELECTRIC CURRENT DISTRIBUTION MEASUREMENT
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    Fuel cells
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    Hydrogen
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    Inert gases
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    Inlet flow
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    Nitrogen
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    Power quality
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    Gas fuel analysis