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Enantioselective assembly of functionalized carbocyclic spirooxindoles using an L-proline derived thiourea organocatalyst
Poopathy Vinayagam,
Published in Royal Society of Chemistry
2015
Volume: 5
   
Issue: 10
Pages: 7370 - 7379
Abstract
Sequential vinylogous Michael addition-cyclization reactions of vinyl malononitriles with isatylidene malononitrile were accomplished using l-proline derived bifunctional thiourea. Cyclohexylidine malononitrile afforded exclusively the single diastereomer with good to excellent enantioselectivity (up to 99% ee) for diverse oxindole spirocyclohexene derivatives. Tetralone derived α,α-dicyano alkene was also employed to access spirocyclic oxindole scaffolds with an excellent level of stereoselectivity (up to 99% ee). © The Royal Society of Chemistry.
About the journal
JournalData powered by TypesetRSC Advances
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN20462069
Open AccessNo
Concepts (14)
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    Addition reactions
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    Cyclization
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    Enantioselectivity
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    Free radical polymerization
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    Scaffolds
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    Bi-functional
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    CYCLIZATION REACTIONS
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    Diastereomers
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    Enantioselective
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    Functionalized
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    MALONONITRILES
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    Michael additions
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    Organocatalysts
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    Thioureas