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Electrochemical reduction of 2,3′-dinitrobenzidine in buffered aqueous methanol
S. Aravamuthan, Chatty Kalidas, Chittoor Sivaramakrishnan Venkatachalam
Published in Kluwer Academic Publishers
1989
Volume: 19
   
Issue: 6
Pages: 897 - 900
Abstract
2,2′-dinitrobenzidine (2,3′-DNB) gives a single diffusion-limited irreversible polarographic wave in buffered aqueous methanol. Microcoulometric experiments indicate a transfer of ten electrons in the reduction and cyclic voltammetric studies show direct proof for the existence of a nitroso intermediate. Based on the results obtained, a suitable mechanism is proposed for the reduction of 2,3′-DNB in buffered methanolic solutions. © 1989 Chapman and Hall Ltd.
About the journal
JournalJournal of Applied Electrochemistry
PublisherKluwer Academic Publishers
ISSN0021891X
Open AccessNo
Concepts (6)
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    Electrochemistry
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    Methanol
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    DIMETHYL FORMAMIDE
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    DINITROBENZIDINE
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    METHANOLIC SOLUTIONS
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    Organic compounds