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Efficient light harvesting in dye sensitized solar cells using broadband surface plasmon resonance of silver nanoparticles with varied shapes and sizes
Ramanujam Kothandraman
Published in Elsevier B.V.
2017
Volume: 193
   
Pages: 288 - 291
Abstract
Plasmonic silver nanoparticles of varied shapes and sizes (v-AgNPs) were synthesized via facile one-pot chemical reduction method and investigated their applicability in dye sensitized solar cells (DSSCs). The synthesized v-AgNPs exhibit broadband absorption over entire visible region owing to their unique localized surface plasmon resonance (LSPR). The photon conversion efficiency (PCE) of DSSCs increased ∼50% by incorporating ∼1 wt% of v-AgNPs in ∼4 μm thin reference photoanode. The enhancement is mainly due to increase in light harvesting ability of plasmonic photoanode as a result of local electromagnetic field enhancement and strong near field scattering effect of v-AgNPs. In addition, the reduction in charge transfer resistance value (R2) further confirms the high charge carrier generation in plasmonic DSSCs. © 2017 Elsevier B.V.
About the journal
JournalData powered by TypesetMaterials Letters
PublisherData powered by TypesetElsevier B.V.
ISSN0167577X
Open AccessNo
Concepts (17)
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    Charge transfer
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    Electromagnetic fields
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    Metal nanoparticles
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    Nanoparticles
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    Nanostructured materials
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    Plasmons
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    Silver
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    Solar cells
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    Solar energy
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    Surface plasmon resonance
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    Synthesis (chemical)
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    BROADBAND ABSORPTION
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    DSSCS
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    LSPR
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    Plasmonic
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    SOLAR ENERGY MATERIALS
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    Dye-sensitized solar cells