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Effect of rare earth ion substitution on the magnetic and transport properties of Pr0.7Re0.04Sr0.26MnO3 (RE = Er3+, Tb3+ and Ho3+)
Published in Springer New York
2004
Volume: 38
   
Issue: 4
Pages: 553 - 557
Abstract
The effect of rare earth ion (RE = Er3+, Tb3+, Ho3+) substitution in Pr0.74Sr0.26MnO 3 (PSMO(0.26)) on the magnetic and transport properties is reported. It is found that even for a small concentration of substitution of Pr 3+ ions by Er3+, Tb3+, or Ho3+ ions there is a significant change in the transport and magnetic properties compared to the parent compound Pr0.74Sr0.26MnO3. The observed changes are attributed to the increase in the average A-site disorder upon substituting smaller ions (ionic radius of Er3+ = 1.062 Å, Ho3+ = 1.072 Å, Tb3+ = 1.095 Å) in place of bigger Pr3+ ion (ionic radius = 1.179 Å). The Ho3+ substituted sample was found to behave anomalously when compared to the other two rare earth ion-substituted (Tb3+ and Er3+) samples. Such anomalous behaviour could most likely be caused by the magnetic coupling of the Ho and Mn ions.
About the journal
JournalData powered by TypesetEuropean Physical Journal B
PublisherData powered by TypesetSpringer New York
ISSN14346028
Open AccessNo
Concepts (17)
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    Cryostats
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    Electric properties
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    Electric resistance
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    Magnetic moments
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    Magnetic properties
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    Magnetization
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    Metal insulator transition
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    RARE EARTH COMPOUNDS
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    Stoichiometry
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    Substitution reactions
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    Transport properties
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    X ray diffraction
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    ION SUBSTITUTION
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    Magnetic coupling
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    Manganites
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    Solid-state method
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    Ions