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Direct use of seawater for rapid methane storage via clathrate (sII) hydrates
Published in Elsevier Ltd
2019
Volume: 235
   
Pages: 21 - 30
Abstract
Storing natural gas in the form of clathrate hydrates (termed as Solidified Natural Gas, SNG) is highly advantageous as it is non-explosive, environmentally benign and offers compact mode of natural gas storage with high volumetric storage capacity. In this work, we demonstrate rapid methane storage in saline water (1.1 mol% NaCl solution) and seawater via clathrate hydrates aided by 5.56 mol% THF in a simple unstirred tank reactor. We report extremely fast hydrate formation kinetics with methane uptake of 89.2 (±2.4) v/v in 13.8 (±2.4) minutes with saline water and 86.3 (±4.3) v/v in 15.1 (±0.8) minutes with natural seawater (t90). This uptake corresponds to an yield of 77.6 (±2.2)% for saline water and 75.0 (±3.4)% for natural seawater system respectively for the stated hydrate growth time. Further, molecular insights of the mixed hydrate formation in presence of NaCl is derived through high-pressure calorimetry, in-situ Raman, and powder X-ray diffraction analysis. Finally, we demonstrate the stability of the hydrate pellet formed employing direct seawater in presence of THF for two weeks. The direct use of natural seawater makes the SNG technology highly attractive to store/transport methane for large-scale storage needs and for low capacity natural gas production facilities like biogas manufacturing plants. © 2018
About the journal
JournalData powered by TypesetApplied Energy
PublisherData powered by TypesetElsevier Ltd
ISSN03062619
Open AccessNo
Concepts (29)
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    Energy storage
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    Enzyme kinetics
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    GAS PLANTS
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    Gases
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    Hydration
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    Methane
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    Natural gas
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    Natural gas well production
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    Natural gasoline plants
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    SEAWATER
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    Sodium chloride
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    X ray powder diffraction
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    Environmentally benign
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    IN-SITU RAMAN SPECTROSCOPY
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    Manufacturing plant
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    METHANE STORAGE
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    Molecular insights
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    NATURAL GAS STORAGE
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    Natural-gas production
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    Powder x ray diffraction
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    Gas hydrates
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    CLATHRATE
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    GAS HYDRATE
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    Gas production
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    GAS STORAGE
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    High pressure
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    Raman spectroscopy
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    Reaction kinetics
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    Salinity