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Crystal structure analysis of (morpholino)(phenyl)(dicyclohexylamino) phosphiniminocyclotrithiazene
G. Sreenivasa Murthy, Talla Venkata Rama Mohan
Published in
2003
Volume: 48
   
Issue: 1
Pages: 68 - 72
Abstract
The title compound (C6H5)(C4H8NO)[N(C6H 11)2]P=N-S3N3 crystallizes in a triclinic crystal system with unit cell parameters a = 9.8884(4) Å, b = 10.6075(1) Å, c = 14.2276(2) Å, α = 78.14(3)°, β = 79.31(1)°, γ = 65.42(2)°, V = 1319.44(6) Å3, Z = 2, and space group P1̄. The cyclotrithiazene ring adopts a "distorted chair" conformation with a deviation of 0.682(7) Å for the tricoordinated sulfur atom. Remarkably, a short exocyclic S-N bond length 1.489(4) Å along with a large P-N-S angle 136.2(3)° are observed with the iminophosphorus moiety. © 2003 MAIK "Nauka/Interperiodica".
About the journal
JournalCrystallography Reports
ISSN10637745
Open AccessNo
Concepts (16)
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    Chemical compound
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    CYCLOTRITHIAZINE
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    Nitrogen
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    Phosphorus
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    Sulfur
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    Unclassified drug
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    Article
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    Atomic particle
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    Chemical analysis
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    Chemical bond
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    Chemical parameters
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    Conformation
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    Crystal
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    Crystal structure
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    Crystallization
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    Structure analysis