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Crystal structure of (diphenyl)(morpholino)phosphiniminocyclotrithiazene
Janaswamy Srinivas, G. Sreenivasa Murthy, Colacot J. Thomas
Published in Kluwer Academic/Plenum Publishers
Volume: 26
Issue: 6
Pages: 403 - 406
The title compound (C6H5)2(OC4H8N)P=N-S 3N3 crystallizes in the space group P1̄ with unit cell parameters a = 9.3900(2), b = 9.4747(1), c = 11.3850(3) Å, α = 95.73(4), β = 96.85(6), γ = 104.26(2)°, and Z = 2. The tricoordinated sulfur of the cyclotrithiazene ring deviates from the mean plane of other skeletal atoms by 0.683(4) Å. The angle at this atom is the smallest in the ring and is enclosed by the longest S-N bonds observed in the ring.
About the journal
JournalJournal of Chemical Crystallography
PublisherKluwer Academic/Plenum Publishers
Open AccessNo