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Chemoselective reduction of α-keto amides using nickel catalysts
Published in Royal Society of Chemistry
2014
Volume: 50
   
Issue: 58
Pages: 7881 - 7884
Abstract
Ni-catalysts are used for the first time to synthesize highly important α-hydroxy amides and β-amino alcohols from α-keto amides by chemoselective and complete reduction using hydrosilanes. Chemoselective complete reduction of α-keto amides in the presence of a simple amide group is a key benefit of these Ni-catalysts. This journal is © the Partner Organisations 2014.
About the journal
JournalData powered by TypesetChemical Communications
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN13597345
Open AccessNo
Concepts (12)
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    Amide
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    Nickel
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    Silane derivative
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    Article
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    Catalyst
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    Chemical parameters
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    Chemical structure
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    CHEMOSELECTIVE REDUCTION
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    Hypothesis
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    Molecular mechanics
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    Reaction time
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    REDUCTION KINETICS