The kinetics of the autocatalysed bromination of anisole (ArH) in CCl <inf>4</inf> has been found to be first order in ArH, Br<inf>2</inf>, and HBr, but with IBr as catalyst, the orders are 1, 1, and 2, respectively; a common mechanism is believed to operate.

Jayaraman Rajaram

Joseph C. Kuriacose

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IIT Madras is a public technical and research university located in Chennai, Tamil Nadu. Founded in 1959, it is recognised as an Institute of National Importance.

IIT Madras has been ranked as the top engineering institute in India for four years in a row by the National Institutional Ranking Framework of the MHRD

It currently offers undergraduate, postgraduate and research degrees across 16 disciplines in Engineering, Sciences, Humanities and Management. About 596 faculty belonging to science and engineering departments and centres of the Institute are engaged in teaching, research and industrial consultancy.

Journal	Journal of the Chemical Society D: Chemical Communications
ISSN	05776171
Open Access	No