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[Au25(SR)18]22-: A noble metal cluster dimer in the gas phase
Ananya Baksi
,
Papri Chakraborty
,
Shridevi Bhat
,
Ganapati Natarajan
,
Pradeep Thalappil
Published in Royal Society of Chemistry
2016
DOI:
10.1039/c6cc03202h
Volume: 52
Issue: 54
Pages: 8397 - 8400
Abstract
We present the first example of dimer formation in the monolayer protected atomically precise cluster system, Au25(SR)18, using ion mobility mass spectrometry. These transient species are shown to be important in explaining chemical reactivity between clusters. © 2016 The Royal Society of Chemistry.
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About the journal
Journal
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Chemical Communications
Publisher
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Royal Society of Chemistry
ISSN
13597345
Open Access
No
Authors (1)
Pradeep Thalappil
Department Of Chemistry
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Mixed-monolayer-protected Au25 clusters with bulky calix[4]arene functionalities
Concepts (14)
Gold
Helium
Silver
Strontium
Absorption spectroscopy
Article
COLLISIONALLY ACTIVATED DISSOCIATION
Crystal structure
Dimerization
Electrospray mass spectrometry
Flow rate
Gas flow
ION MOBILITY SPECTROMETRY
Polymerization
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