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An iodine(iii) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones
Pazhamalai Anbarasan
Published in Royal Society of Chemistry
2015
DOI:
10.1039/c5cc04265h
Volume: 51
Issue: 75
Pages: 14203 - 14206
Abstract
An iodine(iii)-mediated, group-selective oxidative rearrangement of β,β-diarylenamines to α-amino ketones has been accomplished with excellent yield. The developed reaction involves the initial oxidation of enamine to an α-acyloxyimine intermediate and concomitant semipinacol rearrangement. © The Royal Society of Chemistry.
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Citations (1)
References (13)
Related Papers (3)
Journal Details
Authors (1)
Concepts (21)
Related Papers (3)
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About the journal
Journal
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Chemical Communications
Publisher
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Royal Society of Chemistry
ISSN
13597345
Open Access
No
Authors (1)
Pazhamalai Anbarasan
Department Of Chemistry
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An iodine(iii) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones
Concepts (21)
DIPHENYLIODONIUM SALT
Enamine
Iodine
Ketone
Ketone derivative
Scavenger
TRIFLUOROACETIC ANHYDRIDE
Article
Chemical analysis
Chemical reaction
Chemical structure
Competition
Decomposition
Electron
Electrophilicity
Oxidation
OXIDATIVE REARRANGEMENT
Reaction optimization
Reaction time
Room temperature
Synthesis
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