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Aerobic Oxidative Alkenylation of Weak O-Coordinating Arylacetamides with Alkenes via a Rh(III)-Catalyzed C-H Activation
Subramanian Jambu, Ramakrishnan Sivasakthikumaran,
Published in American Chemical Society
PMID: 30763099
Volume: 21
Issue: 5
Pages: 1320 - 1324
A versatile and site-selective rhodium(III)-catalyzed aerobic oxidative alkenylation of arylacetamides including primary, secondary, and tertiary amides having a weak O-coordinating acetamide directing group with alkenes is described. In the reaction, air was utilized as a sole oxidant. The reaction was compatible with activated alkenes and maleimides. © 2019 American Chemical Society.
About the journal
JournalData powered by TypesetOrganic Letters
PublisherData powered by TypesetAmerican Chemical Society
Open AccessNo