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[5,10,15,20-Tetrakis(4-methoxyphenyl)-porphinato]zinc(II) 1,1,2,2-tetra-chloro-ethane solvate
, Karuppaiah Karunanithi, Babu Varghese
Published in
2007
Volume: 63
   
Issue: 12
Pages: m3201 - m3202
Abstract
In the title complex, [Zn(C48H36N4O4)]·C2H2Cl4, the ZnII ion is located on an inversion centre and in an approximately square-planar coordination environment. The tetra-chloro-ethane solvent lies across an inversion centre at the mid-point of the C - C bond. Porphyrin-porphyrin and porphyrin-solvent contacts are dominated by C - H⋯π and C - H⋯O inter-actions, resulting in the formation of a clathrate-like structure. One benzene ring and its meth-oxy substituent are disordered over two positions, with site occupancies of 0.824 (2) and 0.176 (2). In addition, two symmetry-equivalent Cl atoms of the tetra-chloro-ethane solvent also exhibit positional disorder, with site occupancies of 0.635 (2) and 0.365 (2). © International Union of Crystallography 2007.
About the journal
JournalActa Crystallographica Section E: Structure Reports Online
ISSN16005368
Open AccessNo
Concepts (1)
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